And before more people going to argue about insurance, it is not listed on the website of the E-visa application or on the website of the Thai Embassy in London.
Apply for the Non Immigrant O visa based on being married before he makes his way into Thailand and get 90 days of stay, which give enough time to prepare the finances to apply later for the 1 year Exension of Stay based on being married.
Or
Get into Thailand using the 30 day Visa Exempt Entry, apply for Extensions of Stay based on tourism and visiting wife to get the time to prepare the financial requirements for the Non Immigrant O visa based on marriage.