The rules changed as foreigners in Thailand need to have valid/ID. Thailand is one of only a few countries that allows you to retain your old passport during the process. It's also one of the only countries where the process is not online.
She will need a Settlement visa. You will need to meet the financial requirements, provide acceptable accommodation for her and prove the relationship is genuine. She will need to pass a UKVI English test at minimum A1 level and have a TB certificate. It's a fairly lengthy and expensive process, and that's just for the initial visa. For Leave to Remain and finally UK citizenship there a more tests and more costs.