Embassy rules are clear. You must remain in the jurisdiction of the embassy during the entire application period. Leaving is grounds for your application to be rejected with no refund.
The embassies near Thailand are very strict about this and like to do random checks like asking you for a receipt showing you're still in the country or calling you in for an interview.
These are questions you need to be asking your employer. They will tell you if they can convert to non-B inside Thailand (most employers can't or won't) and if they can they will tell you how much time you need left and if you need to apply for extension or not.
Non-immigrant visa is a visa for someone who wants to reside in Thailand. A DTV only allows 180 day stays. It is not a non-immigrant visa obviously. And the law that created it very specifically calls it a tourist visa.
First, you apply for the 90-day non-O visa from the Thai embassy in your home country. You show the amount of money that your embassy requires in your home bank account to meet the requirements.
Then, you travel to Thailand. Use your non-O visa to open a bank ASAP and transfer the money into the account. The money must bein your account for 2 full months when you apply for the 1-year extension.
You will both need your own visa, and you will both need your own bank account with 800,000 baht.