Richard just posted some big news about when you can apply for the new entry program, as well as how quarantine free unvaccinated entry will work.
TLDR : Answer Summary
Recent updates indicate that unvaccinated international travelers can now enter Thailand with only a negative RT-PCR test prior to travel, eliminating the need for pre-arrival proof of a negative test and quarantine upon arrival. They must register for a Thailand Pass with a 5-day hotel booking and insurance coverage of at least $10,000. Additionally, those who upload proof of a recent negative RT-PCR test may be allowed entry without quarantine. The specifics on the Thailand Pass application process and the definition of fully vaccinated (2 or 3 jabs) remain unclear.