Where does your gf live..? With you..? Or at another residence. If she does not live with you then get a copy of her address, the blue book and her ID card and say you live with her. Or go to BKK as discussed above....Yes TM30 is a real pain...
Oh right. Yes there should be no reason why you can't leave Thailand on a Thai passport and enter Australia on an UK passport with an E Visa and return the way you said....back to Thailand....as far as I know anyway.
When did you do this Kurt...?? Security and use of 2 passports has tightened up considerably in 2017. I tried in January 18 and was told that I can't do it so it has changed. It doesn't matter what you have done for the past 20 years....laws do change on occasions.
Man I have a headache....So what I can understand is that she got a single entry 90 day visa that she has already used by entering Thailand. She now goes to immigration and prepares all of the documents required for a year extension and applies for that a min of 21 days (more is advised) . If she needs to exit the country at any time during the 90 days (or the year extension) she will need to apply for a RE-entry permit from immigration or at the airport.
I also have 2 passports and have swapped passports many times by air and at borders....but you can't do it at Thai borders specifically....I went last month and tried it...Cannot...!!