@นิค ********
as you are in the UK...its best you get a Tourist Visa using the new UK Thai E-Visa online application...that will give you up to 90 days in Thailand.
See the TOPIC which I will attach to your post which discusses the UK on line application process.
I do not understand the need to go to Cambodia...unless its Tourism related visit for you both.
The question also is of her ability to obtain a Visa to the UK. Thats another subject you will be exploring and not Thai Visa related. As you are not officially married, you may have some difficulty in her obtaining it.