She is going to go to IT Square Laksi Plaza temporary office, just next to Lak Si station of SRT Dark Red Line as she entered on visa exempt.
She will go here.
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And she can book online here
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She should have been stamped in for 45 days not 30 days currently, after Oct 1, 2022.
The 30 days tourism extension will be added to the current stamp, so you wouldn't lose any day even when you go to apply for one in advance.
Attached is a list of the necessary documents for tourism extension. Most likely she wouldn't be asked for a TM30 receipt unless she has a history of staying in Thailand with covid extension(s).