If your married to a Thai and come to Thailand to see her for 3 months on a SETV and extend that for 30 days.
Could you come in on a 30 day visa exempt and extend that for 60 as your visiting your wife.
You have to get a extension and visit immigration anyway.
But whould save you going to a embassy in your own country and time and money
TLDR : Answer Summary
Yes, you can enter Thailand on a 30-day visa exemption and subsequently apply for a 60-day extension based on visiting your Thai wife. However, when applying for the extension, you may need to provide a Thai marriage certificate or a marriage certificate in Thai script stamped by a consulate if you do not have one from Thailand. Always ensure you have proof of onward travel when flying into Thailand on a visa exemption to avoid any issues at check-in.