You can, but I'd advise arriving early. Need to be done by 3:15 to give you time to get re-entry done. Get the form filled out, make sure you got a photo, and check what they need ie signed copy of passport.
The ask:thailand community, consisting of multiple Q/A groups with over 100,000 members, powers this platform. It is not an official government resource. Our members actively contribute to this resource, and while we strive for accuracy, we cannot guarantee its complete reliability. Assistance to travelers is provided as a community service.