@Tom ***********
as people stated there is no "in country visa activation" AND you can't switch passports by land borders.
You wanna get off the hungarian passport you're on now and use the tourist visa in the auzzie passport you fly out and back.
you stamp out of thailand on the hungarian passport,
you stamp in to another country on the auzzie one,
you stamp out of that country on it
and
then stamping IN to thailand with it to get the tourist visa 60 day entry stamp