TLDR : Answer Summary
To obtain certification for your wife's Thai passport at the Ministry of Foreign Affairs, an appointment is generally not required, but it can depend on the specific office you visit. It is advisable for your wife, as a Thai citizen, to go in person for a faster process. She should bring her Thai ID card and passport, both original and copies, fill out the necessary request form at the Legalization Division, and pay the required fee. The process is usually quicker when handled directly by a Thai national, and some offices may accept walk-ins, although Bangkok offices may have a preference for appointments depending on their workload. For the fastest service, visiting early in the morning or opting for express service is recommended.