*****
and 006 are the two international dialing prefixes for True.
*****
is cheaper, and 006 is supposedly premium quality connections. You dial that prefix, then the country code and number. Of course, you always drop the leading 0 in the phone number whenever you dial internationally, just like you would for Thai phone numbers. So to dial the UK, you would dial
*****
-44-33etc, since the UK country code is 44, and you said the number starts with 33 (dropping the leading zero).